ArticleMolecules (Basel, Switzerland)2025
Fluorimetric Determination of Eosin Y in Water Samples and Drinks Using Deep Eutectic Solvent-Based Liquid-Phase Microextraction.
Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
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4 authors.
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Abstract
An environmentally friendly and highly sensitive analytical method for the determination of the dye Eosin Y (EY) was developed utilizing vortex-assisted liquid-liquid microextraction based on deep eutectic solvents (DESs), combined with fluorescence detection (LPME-FLD). The extraction efficiencies of conventional solvents and various DES systems, composed of tetrabutylammonium bromide (TBAB) and alcohols (hexanol, octanol, and decanol) in different ratios, were systematically compared. DFT calculations provided insights into the most stable forms of EY in solvents of varying polarity. Theoretical Hansen solubility parameters and the COSMO-RS solvation model were applied to assess extraction efficiency. Hansen parameters were obtained via semiempirical PM7 calculations, while BP86/def2-TZVPD DFT computations were employed within the openCOSMO-RS framework. The developed method exhibited a linear calibration range between 0.1 and 130 µg·L
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