Evidence map›Paper›PMID 40853782›Full record

ArticleChemSusChem2025

Cobalt-Catalyzed Green Alkylations of Anilines with Tetrahydrofurans.

Alexandra I Balalaeva, Zechen Wu, Evgeniya Podyacheva, Oleg I Afanasyev, Rajenahally V Jagadeesh, Matthias Beller, Denis Chusov

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemSusChem, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Alexandra I BalalaevaA.N. Nesmeyanov Institute of Organoelement compounds of the Russian Academy of Sciences, Moscow, 119991, Russian Federation.
Zechen WuDepartment of Applied Homogeneous Catalysis, Leibniz-Institut für Katalyse e. V., Albert-Einstein-Straße 29A, 18059, Rostock, Germany.
Evgeniya PodyachevaA.N. Nesmeyanov Institute of Organoelement compounds of the Russian Academy of Sciences, Moscow, 119991, Russian Federation.
Oleg I AfanasyevA.N. Nesmeyanov Institute of Organoelement compounds of the Russian Academy of Sciences, Moscow, 119991, Russian Federation.
Rajenahally V JagadeeshDepartment of Applied Homogeneous Catalysis, Leibniz-Institut für Katalyse e. V., Albert-Einstein-Straße 29A, 18059, Rostock, Germany.
Matthias BellerDepartment of Applied Homogeneous Catalysis, Leibniz-Institut für Katalyse e. V., Albert-Einstein-Straße 29A, 18059, Rostock, Germany.ORCID https://orcid.org/0000-0001-5709-0965
Denis ChusovA.N. Nesmeyanov Institute of Organoelement compounds of the Russian Academy of Sciences, Moscow, 119991, Russian Federation.ORCID https://orcid.org/0000-0001-6770-5484

Funding

Ministry of Science and Higher Education 075-00276-25-00
6 · The paper itself

Abstract

The use of bio-renewable resources as starting materials and reagents in synthetic chemistry is an important area for sustainable development. The use of tetrahydrofuran (THF) and 2-methyltetrahydrofuran (2-MeTHF) is reported, which can be obtained from lignocellulosic biomass, as potential alkylating agents for anilines. The developed N-alkylation process is catalyzed by the readily available cobalt salts and employs industrially available syngas as a reducing agent. The reported approach allows for the green and cost-effective production of N-alkylanilines from readily available feedstocks.

Indexed as

alkylationbiomassrenewable resourcessyngastetrahydrofuran

Identifiers

PMID40853782
PMCPMC12487734

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.