ArticleAdvanced materials (Deerfield Beach, Fla.)2025
Copper Catalysts Inherit and Retain Precatalyst Morphology in Extended CO Electroreduction to n-Propanol.
Article in Advanced materials (Deerfield Beach, Fla.), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Copper Catalysts Inherit and Retain Precatalyst Morphology in Extended CO Electroreduction to n-Propanol.Advanced materials (Deerfield Beach, Fla.) · 2025Article
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13 authors.
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Abstract
Copper catalyst morphology, faceting, and oxidation state are each known to impact selectivity in the electroreduction of CO. Copper oxide precatalysts are synthesized using flash Joule heating and rapid cooling, and it is observed that temperature ramp rates can be used to control morphology, enabling us to implement ≈10 nm-sized intragrain features within ≈35 nm grains. It is found that the structural features of the precatalysts are substantially transferred to Cu catalysts that are formed when they are employed in CO electroreduction in a membrane electrode assembly electrolyzer. The catalysts achieve ≈35% faradaic efficiency to n-propanol, among the highest selectivities to C
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