Evidence map›Paper›PMID 40844234›Full record

ReviewAngewandte Chemie (International ed. in English)2025

Organic Spin-State Photoswitches.

Takuma Miyamura, Joël Schlecht, Oliver Dumele

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Review
  3. Air-Stable Luminescent Schlenk Diradical With Triplet Ground State.Angewandte Chemie (International ed. in English) · 2026
    Article
  4. Article
  5. Article
  6. Organic Spin-State Photoswitches.Angewandte Chemie (International ed. in English) · 2025
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Takuma Miyamura *Department of Organic Chemistry, Albert-Ludwigs-Universität Freiburg, Alberstrasse 21, 79104, Freiburg, Germany.ORCID https://orcid.org/0009-0004-7134-924X
Joël Schlecht *Department of Organic Chemistry, Albert-Ludwigs-Universität Freiburg, Alberstrasse 21, 79104, Freiburg, Germany.
Oliver DumeleDepartment of Organic Chemistry, Albert-Ludwigs-Universität Freiburg, Alberstrasse 21, 79104, Freiburg, Germany.ORCID https://orcid.org/0000-0002-3277-6570

Funding

Fonds der Chemischen Industrie DozentenpreisGerman Academic Exchange Service 91897284
6 · The paper itself

Abstract

Organic spin-state photoswitches represent an emerging class of molecular systems capable of reversibly modulating electronic spin states using light. This review provides a comprehensive overview of the fundamental mechanisms underlying two principal switching modes: photoconformational and photochemical. Emphasis is placed on their structural design, magnetic behavior, and the methods used for their characterization, including electron paramagnetic resonance (EPR) and UV-vis spectroscopy. Selected examples illustrate the ability of these systems to control spin-polarized states, alter magnetic exchange interactions, or switch between singlet and triplet spin states upon photoirradiation. The review also discusses challenges related to thermal stability, bistability, and operation under ambient conditions. Emerging strategies for integrating photoswitches with persistent radicals or redox-active units are highlighted for their potential in molecular electronics and quantum information science. Notably, light-induced diradical species in such systems are gaining recognition as molecular qubits, offering long coherence times and spectroscopic addressability essential for quantum gate operations. By exploring design principles and technological implications, this review underscores the unique position of all-organic spin-state photoswitches at the intersection of photochemistry, magnetism, and quantum materials development.

Indexed as

ChromophoresDiradicalsMolecular magnetismPhotoswitchesSpin materials

Identifiers

PMID40844234
PMCPMC12435443

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.