Hyperspectral Information Extraction With Full Resolution From Arbitrary Photographs.

Because optical spectrometers capture abundant molecular, biological, and physical information beyond images, ongoing efforts focus on both algorithmic and hardware approaches to obtain detailed spectral information. Spectral reconstruction from red-green-blue (RGB) values acquired by conventional trichromatic cameras has been an active area of study. However, the resultant spectral profile is often affected not only by the unknown spectral properties of the sample itself, but also by light conditions, device characteristics, and image file formats. Existing machine learning models for spectral reconstruction are further limited in generalizability due to their reliance on task-specific training data or fixed models. Advanced spectrometer hardware employing sophisticated nanofabricated components also constrains scalability and affordability. Here we introduce a general computational framework, co-designed with spectrally incoherent color reference charts, to recover the spectral information of an arbitrary sample from a single-shot photo in the visible range. The mutual optimization of reference color selection and the computational algorithm eliminates the need for training data or pretrained models. In transmission mode, altered RGB values of reference colors are used to recover the spectral intensity of the sample, achieving spectral resolution comparable to that of scientific spectrometers. In reflection mode, a spectral hypercube of the sample can be constructed from a single-shot photo, analogous to hyperspectral imaging. The reported computational photography spectrometry has the potential to make optical spectroscopy and hyperspectral imaging accessible using off-the-shelf smartphones.