ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
Dendronized Encapsulation with Hierarchical Rigidification Enabling Robust Solution Room-Temperature Phosphorescence, Efficient Electroluminescence and Ultralong Afterglow.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Dendronized Encapsulation with Hierarchical Rigidification Enabling Robust Solution Room-Temperature Phosphorescence, Efficient Electroluminescence and Ultralong Afterglow.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
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Authors and funding
9 authors.
Funding
Abstract
Organic room-temperature phosphorescence (RTP) materials face a fundamental challenge: their environment-specific phosphorescent behavior fundamentally conflicts with the growing demand for multifunctional materials. To overcome this limitation, a multiscale confinement strategy is developed that integrates intramolecular flexible encapsulation with intermolecular rigid immobilization. Dendronized donor-acceptor molecules are engineered with alkyl-chain-carbazole dendrons to achieve intramolecular encapsulation. This design enables abundant spatial interactions, balancing conformational flexibility (for solution processing) and emission rigidity. Multiscale confinement via molecular aggregation and poly(methyl methacrylate) (PMMA) doping further enhances rigidification. Together, these mechanisms suppress nonradiative transitions across four temporal orders of magnitude (10
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