ArticleACS polymers Au2025
Unlocking the Potential of
Article in ACS polymers Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- Engineering porous organic polymers for enhanced COChemical science · 2026Review
- Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This study presents the synthesis and construction of two innovative conjugated microporous polymers (CMPs), TPBZ-PyT CMP and TPBZ-TPET CMP, which incorporate pyrene (Py) and tetraphenylethene (TPE) subunits, respectively. These subunits are selected for their complementary properties, with the TPE moiety offering enhanced flexibility compared to the more rigid Py structure. The flexibility of TPE is hypothesized to improve the adsorption performance of the CMPs for removing rhodamine B (RhB) dye from aqueous solutions. The TPBZ CMPs were characterized using a suite of techniques, including Brunauer-Emmett-Teller (BET) surface area analysis, SEM, and FTIR. Batch adsorption experiments demonstrated that TPBZ-TPET CMP achieved a remarkable RhB removal efficiency of 49.49% within the first 30 min, reaching 98.72% after 60 min. In comparison, TPBZ-PyT CMP attained a maximum removal efficiency of 53.49% at the 60 min mark. Kinetic studies revealed distinct adsorption mechanisms for the two TPBZ CMPs. The adsorption process for TPBZ-TPET CMP was analyzed using a pseudo-second-order model, showing that chemisorption is the dominant mechanism. Meanwhile, TPBZ-PyT CMP exhibited pseudo-first-order kinetics, suggesting a different rate-limiting step. These findings highlight the critical role of subunit flexibility in designing CMPs for enhanced adsorption performance. The superior efficiency of TPBZ-TPET CMP underscores the potential of flexibility-engineered CMPs in advancing water purification technologies and addressing dye contamination in aquatic environments.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.