Evidence map›Paper›PMID 40820652›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Enhancing the Self-Assembly of Step-Growth Polymers by Narrowing Their Molar Mass Distribution: A Dynamic Bond-Mediated Approach.

Lucas Polo Fonseca, Shaghayegh Hamzehlou, Olaia Garagarza, Daniele Mantione, Aritz Lamas, Xabier Lopez de Pariza, Fermin Elizalde, Marta Ximenis Campins, Amaia Agirre, Gabriel Perli and 1 more

Abstract read
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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Lucas Polo FonsecaPOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.ORCID https://orcid.org/0000-0003-3140-8589
Shaghayegh HamzehlouPOLYMAT, University of the Basque Country UPV/EHU, Joxe Mari Korta zentroa, Tolosa Hiribidea 72, Donostia-San Sebastián, 20018, Spain.
Olaia GaragarzaPOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.
Daniele MantioneIKERBASQUE, Basque Foundation for Science, Bilbao, 48009, Spain.
Aritz LamasPOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.
Xabier Lopez de ParizaPOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.
Fermin ElizaldePOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.
Marta Ximenis CampinsPOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.
Amaia AgirrePOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.
Gabriel PerliPOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.
Haritz SardonPOLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizábal, 3, Donostia-San Sebastian, 20018, Spain.ORCID https://orcid.org/0000-0002-6268-0916

Funding

Advanced Manufacturing Research Fellowship ProgrammeEuropean Union's HorizonGipuzkoa Fellows Programme G75067454Marie Skłodowska-Curie 101034379Marie Skłodowska-Curie 101154935Marie Skłodowska-Curie 2023027561
6 · The paper itself

Abstract

Step-growth polymerization (SGP) typically produces polymers with exceptional versatility in terms of applications, but its inherently uncontrolled nature leads to broad molecular weight distributions (Đ) and consequently polymers with poor nanostructure control in comparison to chain growth polymers. In this study, we provide a solution to this long-lasting problem by introducing a new concept, asymmetric dynamic bond mediated polymerization (ADBP). In this case, the polymerization between asymmetric and reversibly deactivated AA'-type dielectrophiles and B

Indexed as

Dynamic‐bondNarrow dispersitiesPhase separationStep‐growth polymers

Identifiers

PMID40820652
PMCPMC12455433

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.