Evidence map›Paper›PMID 40799488›Full record

ArticleACS electrochemistry2025

Electrochemical Ammoxidation of Unprotected Glycosides.

Imke M A Bartels, Md Asmaul Hoque, J Prathap Kaniraj, Mathew R Johnson, Sebastian B Beil, Shannon S Stahl, Martin D Witte, Adriaan J Minnaard

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ACS electrochemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Imke M A BartelsStratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands.
Md Asmaul HoqueDepartment of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States.ORCID https://orcid.org/0000-0003-3942-863X
J Prathap KanirajStratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands.
Mathew R JohnsonDepartment of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States.
Sebastian B BeilStratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands.ORCID https://orcid.org/0000-0003-0373-3843
Shannon S StahlDepartment of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States.ORCID https://orcid.org/0000-0002-9000-7665
Martin D WitteStratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands.ORCID https://orcid.org/0000-0003-4660-2974
Adriaan J MinnaardStratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands.ORCID https://orcid.org/0000-0002-5966-1300

Funding

Catalytic Redox Reactions for Pharmaceutical SynthesisR35GM134929 · NIGMS · UNIVERSITY OF WISCONSIN-MADISON · PI Shannon S Stahl · 2020 to 2026
$4.3M
NIGMS NIH HHS R35 GM134929
6 · The paper itself

Abstract

Cyano-sugars are useful carbohydrate building blocks. Here, we report an electrocatalytic method to oxidize the primary alcohols of unprotected glycosides to the corresponding nitrile using 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO) as a mediator and ammonium tetrafluoroborate as the ammonia source. Monosaccharides and disaccharides undergo successful reactions in an acetonitrile/pyridine solvent mixture at room temperature under constant current electrolysis.

Indexed as

ammoxidationcarbohydratesElectrocatalytic oxidationnitrilesTEMPO

Identifiers

PMID40799488
PMCPMC12337100

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.