ReviewACS electrochemistry2025
Diffusional Voltammetry in Finite Spaces.
Review in ACS electrochemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- Measuring Electrode Kinetics Under Spatial Confinement. Application of Pulse Voltammetry to Different Mass Transport Modes Using Butler-Volmer and Marcus-Hush-Chidsey Frameworks.ACS measurement science au · 2026Article
- Turning the FeFe hydrogenase fromProceedings of the National Academy of Sciences of the United States of America · 2025Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The pore structure is a key design parameter for optimizing electrocatalytic systems that utilize porous electrodes, necessitating characterization at scales relevant to catalysis (∼0.1-100 μm). In this Review, we examine how diffusion during faradaic processes is impacted by the electrode pore geometry, defined by the concavity/convexity of its surface curvature, and by pore size, defined by the finiteness of the diffusion domain. We briefly outline experimental considerations for correlating experimental and simulated data from porous electrodes, and then outline the current theories for modeling diffusional voltammetry at various electrodes with finite diffusion spaces (direct problem), including planar redox-active films, concave inverse opals and hollow tubes, and convex pillar arrays and particle arrays. Finally, we describe how these theoretical frameworks can be applied to characterize the electrode pore structure by analyzing experimental voltammetric current responses (inverse problem).
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.