Evidence map›Paper›PMID 40792565›Full record

ArticleInorganic chemistry2025

Probing Mn Precatalyst Activation through Time-Resolved Spectroscopy: A Quantitative Evaluation of the Effects of CO and PPh

Benjamin R O'Donoghue, Stefan Flesch, Eimear Courtney, Shweta Choudhary, Jonathan B Eastwood, Katrina Mackey, Leticia M Pardo, Ian P Clark, Partha Malakar, Gregory M Greetham and 5 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Inorganic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Benjamin R O'DonoghueDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.
Stefan FleschDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.ORCID 0000-0002-4220-236X
Eimear CourtneySchool of Chemistry, Analytical & Biological Chemistry Facility, University College Cork, Cork T12 YN60, Ireland.ORCID 0000-0002-8619-3872
Shweta ChoudharyDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.
Jonathan B EastwoodDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.ORCID 0000-0001-5586-7697
Katrina MackeySchool of Chemistry, Analytical & Biological Chemistry Facility, University College Cork, Cork T12 YN60, Ireland.
Leticia M PardoSchool of Chemistry, Analytical & Biological Chemistry Facility, University College Cork, Cork T12 YN60, Ireland.
Ian P ClarkCentral Laser Facility, STFC Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Oxfordshire, Didcot OX11 0QX, U.K.ORCID 0000-0002-0105-4743
Partha MalakarCentral Laser Facility, STFC Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Oxfordshire, Didcot OX11 0QX, U.K.ORCID 0000-0001-6874-7010
Gregory M GreethamCentral Laser Facility, STFC Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Oxfordshire, Didcot OX11 0QX, U.K.ORCID 0000-0002-1852-3403
Adrian C WhitwoodDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.ORCID 0000-0002-5132-5468
Richard J GammonsDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.
Gerard P McGlackenSchool of Chemistry, Analytical & Biological Chemistry Facility, University College Cork, Cork T12 YN60, Ireland.ORCID 0000-0002-7821-0804
Ian J S FairlambDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.ORCID 0000-0002-7555-2761
Jason M LynamDepartment of Chemistry, University of York, Heslington, YorkYO10 5DD, U.K.ORCID 0000-0003-0103-9479

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

An investigation into the effect of a phosphine coligand on the activation of precatalysts for manganese-catalyzed C-H bond functionalization is reported. Although simple precatalysts [MnBr(CO)

Identifiers

PMID40792565
PMCPMC12381853

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.