Evidence map›Paper›PMID 40792490›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Switching-Off to Switching-On Triplet Formation Through Singlet-Triplet Intersystem Crossing in Porphyrin Metal-Organic Frameworks.

Sreehari Surendran Rajasree, Saied Md Pratik, Venkatesh Gude, Jierui Yu, Brendan MacAins, David J Gosztola, H Christopher Fry, Pravas Deria

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Sreehari Surendran RajasreeSchool of Chemical and Biomolecular Sciences, Southern Illinois University Carbondale, 1245 Lincoln Dr, Carbondale, Illinois, 62901, USA.ORCID https://orcid.org/0000-0002-7318-466X
Saied Md PratikDepartment of Chemistry, University of Minnesota, Minneapolis, Minnesota, 55455, USA.
Venkatesh GudeSchool of Chemical and Biomolecular Sciences, Southern Illinois University Carbondale, 1245 Lincoln Dr, Carbondale, Illinois, 62901, USA.
Jierui YuSchool of Chemical and Biomolecular Sciences, Southern Illinois University Carbondale, 1245 Lincoln Dr, Carbondale, Illinois, 62901, USA.
Brendan MacAinsSchool of Chemical and Biomolecular Sciences, Southern Illinois University Carbondale, 1245 Lincoln Dr, Carbondale, Illinois, 62901, USA.
David J GosztolaCenter for Nanoscale Materials, Argonne National Laboratory, Lemont, Illinois, 60439, USA.
H Christopher FryCenter for Nanoscale Materials, Argonne National Laboratory, Lemont, Illinois, 60439, USA.
Pravas DeriaSchool of Chemical and Biomolecular Sciences, Southern Illinois University Carbondale, 1245 Lincoln Dr, Carbondale, Illinois, 62901, USA.

Funding

Bioinspired selective heterogeneous organic photoredox catalysisR15GM148938 · NIGMS · SOUTHERN ILLINOIS UNIVERSITY CARBONDALE · PI DERIA, PRAVAS · 2022 to 2024
$519k
National Science Foundation CHE-1944903NIGMS NIH HHS R15 GM148938NIH HHS 1R15GM148938-01U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences DE-AC02-06CH11357
6 · The paper itself

Abstract

Solid-state artificial photosystems need precise control over their singlet or triplet excited states to enable desired photochemical transformations. While persistent triplets are often selected to drive chemical bond formation or spin-specific photoreactions, singlets can allow for ambient applications. Among different heterogeneous systems, metal-organic frameworks (MOFs) offer a solution-stable platform with many benefits, including large chemically accessible interior surfaces where excitons can be transferred from their original formation sites. Porphyrins demonstrate high intersystem crossing efficiency, with QY

Indexed as

Artificial photosystemPorphyrin MOFSinglet–triplet ISCTopological controlTriplet dynamics

Identifiers

PMID40792490
PMCPMC12670875

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.