ArticleAngewandte Chemie (International ed. in English)2025
The Pentafluorophenyl Cation: A Superelectrophile and Diradical.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
1 citing paper in PubMed.
- The Pentafluorophenyl Cation: A Superelectrophile and Diradical.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
5 authors.
Funding
Abstract
We report the first direct observation of the pentafluorophenyl cation in the gas phase via vacuum ultraviolet (VUV) photoionization (PI) of the thermally generated pentafluorophenyl radical. The reactive intermediates and stable reaction products were characterized utilizing photoelectron photoion coincidence (PEPICO) spectroscopy with synchrotron radiation. Electron removal from the pentafluorophenyl radical yields the cation with an adiabatic ionization energy (AIE) of 9.84 ± 0.02 eV. Threshold photoelectron spectra combined with high-level ab-initio calculations show that the cation is described as a π
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Registered trials
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