ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
Orchestrating Multi-Ångstrom Spaced Cu─Ni Dual-Atom Pair for Synergistic C─H Activation in Direct Methane Oxidation to Methanol.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Orchestrating Multi-Ångstrom Spaced Cu─Ni Dual-Atom Pair for Synergistic C─H Activation in Direct Methane Oxidation to Methanol.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
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5 authors.
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Abstract
Direct and efficient methane oxidation to methanol is an appealing route for upgrading abundant methane resources while acquiring building blocks of clean fuels and chemicals. However, owing to its highly symmetrical nature imparted chemical stability and steric hindrance, the design of multi-ångstrom (<3.0 Å) spaced active species capable of activating its first C-H bond remains a fundamental challenge. Herein, Cu-Ni dual-atom Pair is constructed using defect engineering and a stepwise deposition method over indium oxide to precisely modulate the C-H polarization with the Cu atom showing affinity to H end and Ni anchoring the C side. The optimal CuNi/InNT achieves an oxygenates (CH
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