ArticleChemical science2025
Reversible transformation of single-crystal two-dimensional polymer framework for photo/thermal reversible photolithography.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The preparation of large-sized single crystals of two-dimensional covalent organic frameworks (2D COFs) or 2D polymers is already a highly challenging task, and the study of reversible transformations of such materials in their single-crystalline state remains an unexplored research area. Herein, we demonstrate a successful photo/thermal reversible transformation between a 2D polymer framework and its monomer while maintaining single-crystal integrity. By photopolymerization under UV light and thermal depolymerization at elevated temperatures, repeatable structural transitions were achieved in a single-crystal state. Leveraging this reversible behavior, a thin-film material with rewritable photolithographic properties was developed. Patterns could be inscribed using UV light and erased or modified through heating, showing excellent reversibility. These findings deepen the understanding of reversible covalent bond transformations and underscore their potential applications in photolithography and advanced manufacturing technologies.
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Registered trials
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