Gold(I) Complexes of ImPyDippDipp and ImPyMesMes: Biaryl L‑Shaped N‑Heterocyclic Carbene Analogues of IPr and IMes.

Yuzhuo Sha, Wenchao Chu, Tongliang Zhou, Roger Lalancette, Roman Szostak, Michal Szostak

Abstract read

In one paragraph

Article in Organometallics, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it

0cells of the map it votes in

2citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

Chiral Imidazo[1,5‑JACS Au · 2025
Article
IPr**Organometallics · 2025
Article

4 · The record

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5 · Who and what money

Authors and funding

6 authors.

Yuzhuo ShaDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.

Wenchao ChuDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.

Tongliang ZhouDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.ORCID https://orcid.org/0000-0002-7334-7078

Roger LalancetteDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.ORCID https://orcid.org/0000-0002-3470-532X

Roman SzostakDepartment of Chemistry, Wroclaw University, F. Joliot-Curie 14, Wroclaw 50-383, Poland.

Michal SzostakDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.ORCID https://orcid.org/0000-0002-9650-9690

Funding

Catalytic Methods for Organic SynthesisR35GM133326 · NIGMS · RUTGERS THE STATE UNIV OF NJ NEWARK · PI Michal Szostak · 2019 to 2026

$2.7M

NIGMS NIH HHS R35 GM133326

6 · The paper itself

Abstract

Imidazol-2-ylidenes, IPr and IMes, represent by far the most important and widely utilized N-heterocyclic carbenes in organic synthesis and catalysis. Herein, we report the synthesis, catalytic activity, and structural and electronic characterization of ImPyDippDipp and ImPyMesMes, sterically bulky and easily accessible biaryl L-shaped N-heterocyclic carbene analogues of IPr and IMes. These ligands exploit the rigid imidazo-[1,5-

Identifiers

PMID40785983

DOI10.1021/acs.organomet.5c00093

PMCPMC12333412

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LicenceCC BY

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.