Three-Way Chemodivergent Derivatization of Non-Activated 2-Arylphenyl Benzyl Ethers.

Marta Solas, Carlos Sedano, Samuel Suárez-Pantiga, Sofia Kiriakidi, Carlos Silva-López, Roberto Sanz

Abstract read

In one paragraph

Article in The Journal of organic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

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4 · The record

Corrections and comments

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5 · Who and what money

Authors and funding

6 authors.

Marta SolasÁrea de Química Orgánica, Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Pza. Misael Bañuelos s/n, 09001 Burgos, Spain.

Carlos SedanoÁrea de Química Orgánica, Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Pza. Misael Bañuelos s/n, 09001 Burgos, Spain.

Samuel Suárez-PantigaÁrea de Química Orgánica, Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Pza. Misael Bañuelos s/n, 09001 Burgos, Spain.ORCID 0000-0002-4249-7807

Sofia KiriakidiDepartamento de Química Orgánica. Facultad de Química, Universidade de Vigo, Campus Universitario, 36310 Vigo, Spain.ORCID 0000-0003-2509-3277

Carlos Silva-LópezDepartamento de Química Orgánica. Facultad de Química, Universidade de Vigo, Campus Universitario, 36310 Vigo, Spain.ORCID 0000-0003-4955-9844

Roberto SanzÁrea de Química Orgánica, Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Pza. Misael Bañuelos s/n, 09001 Burgos, Spain.ORCID 0000-0003-2830-0892

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A thermally controlled rare chemodivergent mechanistic trifurcation has been found through experimental and computational efforts. Notably, one of the available paths in this three-way mechanism allows for an unprecedented dearomatization reactivity of non-activated 2-arylphenyl benzyl ethers under very mild thermal conditions after Csp

Identifiers

PMID40773667

DOI10.1021/acs.joc.5c01460

PMCPMC12381931

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.