Evidence map›Paper›PMID 40772323›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Synergistic Gold-Silicon Catalysis: Unravelling Alkynyl Gold Reactivity and Application to the High-Performance C-Alkynylation of Glycals.

Mathieu Pascaretti, Eliot Starck, Andres Padilla Hernandez, Romain Pertschi, Catherine Taillier, Aurélien Blanc, Jean-Marc Weibel, Patrick Pale, Vincent Dalla

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Mathieu PascarettiCOSyS, Institut de Chimie, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg, 67081, France.
Eliot StarckCOSyS, Institut de Chimie, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg, 67081, France.
Andres Padilla HernandezCOSyS, Institut de Chimie, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg, 67081, France.
Romain PertschiSynthèse Organique Métallo-induite et Hétérochimie (SOMHet), Laboratoire d'Innovation Thérapeutique, UMR 7200, Faculté de Pharmacie, Université de Strasbourg, 74 route du Rhin, Illkirch-Graffenstaden, 67400, France.
Catherine TaillierUniversité Le Havre Normandie, Normandie Univ., URCOM UR 3221, Le Havre, 76600, France.
Aurélien BlancCOSyS, Institut de Chimie, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg, 67081, France.
Jean-Marc WeibelCOSyS, Institut de Chimie, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg, 67081, France.
Patrick PaleCOSyS, Institut de Chimie, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg, 67081, France.ORCID https://orcid.org/0000-0002-3924-530X
Vincent DallaUniversité Le Havre Normandie, Normandie Univ., URCOM UR 3221, Le Havre, 76600, France.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Within the synergistic gold-silicon catalysis concept, we have reported here the efficient and highly α-stereoselective Au-Si-catalyzed alkyne transfer from 1-trimethylsilylalkynes to glycals, at room temperature and at low loading (0.2-1 mol%). The synthesized and bench-stable (F

Indexed as

alkynylationC‐glycosidesgoldligand effectsynergistic catalysis

Identifiers

PMID40772323
PMCPMC12498081

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.