ArticleRSC advances2025
Methyl itaconate-anthracene adducts (MIAs) facilitate the enantiomeric separation of 1,1'-bi-2-naphthols
Article in RSC advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
1,1'-bi-2-naphthols (BINOLs) and their derivatives have been extensively studied over the years. Enantiopure BINOLs are crucial in asymmetric synthesis, circularly polarized luminescent dyes, and charge transfer host systems. Several methods, including asymmetric oxidative coupling, enzymatic resolution, and chemical resolution, have been explored to prepare enantiopure BINOLs. Chemical resolution by chromatography offers the advantage of obtaining both enantiomers with high purity. Herein, we employed methyl itaconate-anthracene adducts (MIAs) as chiral resolving agents (CRAs) for the resolution of racemic BINOLs. Diastereomers were obtained
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