ArticleRoyal Society open science2025
Reusable Mg supported IRMOF-3 as a heterogeneous nanocatalyst for chemoselective reduction of biomass-based aldehydes and ketones to alcohols under mild conditions.
Article in Royal Society open science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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2 authors.
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Abstract
A novel, durable heterogeneous magnesium-supported catalyst, IRMOF-3@Di(2-pyridyl) ketone@Mg(II) (Di(2-pyridyl) ketone: Di-2pyk), was effectively synthesized using a convenient approach and fully characterized utilizing chemo-physical analysis techniques such as powder X-ray diffraction analysis, attenuated total reflection infrared spectroscopy, field emission scanning electron microscopy with energy-dispersive spectroscopy, transmission electron microscopy, CHN analysis, inductively coupled plasma optical emission spectroscopy, thermogravimetric analysis and Brunauer-Emmett-Teller measurements. This metal-organic framework-based nanocatalyst displayed excellent catalytic behaviour in chemoselective hydrogenation of five biomass-based carbonyl compounds of furfural, cinnamaldehyde, levulinic acid, vanillin and citral in addition to a variety of aliphatic, aromatic, and α,β-unsaturated aldehydes and ketones at room temperature in water in the presence of sodium borohydride as a mild and safe hydrogen source reagent. The leaching and reusability experiments of this catalyst exhibited stability and reactivity after four runs.
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