ArticleMikrochimica acta2025
Atomically dispersed Fe-Mn dual sites in N-doped carbon nanozymes with peroxidase-mimetic activity for the determination of thiocyanate.
Article in Mikrochimica acta, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
FeMn dual-active-site single-atom catalyst (FeMn-N-C), featuring manganese-enhanced Fe-N-doped carbon with abundant FeMn-N4 and C-N active groups, was fabricated via hydrothermal synthesis followed by high-temperature pyrolysis. Thiocyanate (SCN⁻) can be adsorbed onto the FeMn-N-C surface by binding to Fe/Mn atoms, blocking the active sites of the mimic peroxidase and thereby inhibiting the corresponding chromogenic reaction of 3,3',5,5'-tetramethylbenzidine, achieving rapid and sensitive colorimetric detection of SCN⁻. Under optimal conditions, the established biosensor exhibited a linear range of 0.2-11 μmol L
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