ArticleNature communications2025
Uranium-stibinidiide, -stibinidene, and -stibido multiple bonds and uranium-nitride formation from multimetallic diuranium-distibene-mediated dinitrogen cleavage.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- All-metal aromaticity of cyclo-BiNature chemistry · 2026Article
- Field-induced non-linear magnetic responses of all-metal Jellium σ-aromats.Nature communications · 2026Article
- Transient Triamidoamine Neptunium(V)-Mono(Imido) Complexes: C-H Activations and Hydrogen Atom Transfer Driven by Effective Nuclear Charge.Journal of the American Chemical Society · 2026Article
- A Consistent Approach to One Coordinate Pnictide Moieties M≡PnAngewandte Chemie (International ed. in English) · 2026Article
- Isolable f-element diphosphene complexes by phosphinidene group transfer and coupling at uranium.Nature communications · 2025Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Although uranium-nitrogen multiple bonding is well developed, there are far fewer uranium-phosphorus and -arsenic multiple bonds, and none for antimony, even in spectroscopic scenarios. Here, we report straightforward syntheses of uranium-stibido, -stibinidiide, -distibene, and -stibinidene derivatives containing single, double, and pseudo-triple bond interactions. Quantum chemical calculations suggest that these uranium-antimony multiple bonds are more covalent than thorium-antimony congeners, due to superior spatial and energy matching of uranium and antimony frontier orbitals, but comparison to isostructural uranium-phosphorus and -arsenic analogues suggests that for uranium moving from phosphorus to arsenic to antimony the spatial overlap term reduces but the orbital energy matching improves. Reduction of the distibene complex results in loss of the antimony-component and multimetallic activation and cleavage of dinitrogen to nitride. This constitutes an uncommon mode of reactivity for uranium that is co-facilitated by the distibene and potassium ions.
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Registered trials
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