ArticleNature chemistry2025
Isolation of halogen-substituted silylium ions.
Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Germylium Catalyzed Dehydrofluorination Reactions of Fluorinated Alkanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- A Strong Lewis Acidic Diethylsilylium Catalyst for Direct Sulfonamidation of Challenging Ketones.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Synthesis and Reactivity of Boron Triflate and Bistriflimide Complexes Bearing TwoInorganic chemistry · 2026Article
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Authors and funding
6 authors.
Funding
Abstract
The existence and intermediacy of halogen-substituted silylium ions have been the subject of speculation for decades. These elusive reactive intermediates are synthetically attractive because of their computationally predicted super Lewis acidity and their relevance in several synthetic transformations such as recycling of waste from the Müller-Rochow process and hydrodefluorination of per- and polyfluoroalkyl substances. Here we report the generation and characterization of all halogen-substituted silylium ions of type [Alk
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