ArticleScience advances2025
Ambient catalyst-free conversion of methane to methanol by water radical cations.
Article in Science advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The trial behind it
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Who cites it
3 citing papers in PubMed.
- Water-Derived Radical Species Initiate Six-Electron Oxidation of Cyclic Ketones in Microdroplets.Angewandte Chemie (International ed. in English) · 2026Article
- Catalytic conversion of methane to methanol: recent advances in MOF-based catalysts, oxidant strategies, and process optimization.RSC advances · 2026Review
- Unraveling Water-Defect Coupled Degradation via Deuterium Isotope Labeling in Prussian Blue Analogue Cathodes for Long-Life Sodium-Ion Batteries.Angewandte Chemie (International ed. in English) · 2026Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Methane combustion contributes 30% to global warming, making its conversion to cleaner chemicals a critical challenge. Here, we report a catalyst-free ambient conversion of methane to methanol with a remarkable yield exceeding 650 millimoles per hour and a high conversion rate of ~35%, achieved using in situ-generated water dimer radical cations, [Formula: see text] , in a specially designed batch reactor operating under mild conditions. In a single run, the reactor was typically operated for 10 minutes. The atom efficiency for hydrogen in our approach for methanol synthesis is ~67%. Hydrogen gas is the by-product, produced at a rate of over 2 millimoles per hour. Compared to the previously reported catalytic methods, our production yields are up by between 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.