Evidence map›Paper›PMID 40736128›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

Enhanced Reactivity of N-heterocyclic Halophosphines and Phosphenium Cations: The Activation of Carbon─Heteroatom and Boron─Heteroatom Bonds.

Maksim A Samsonov, Jan Vrána, Petr Švec, Vlastimil Němec, Eliška Procházková, Josef Cvačka, Aleš Růžička

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Accessing chiral NHC-boranes by abstraction of CDalton transactions (Cambridge, England : 2003) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Maksim A SamsonovDepartment of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, 53209, Czech Republic.ORCID https://orcid.org/0000-0002-3839-5939
Jan VránaDepartment of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, 53209, Czech Republic.
Petr ŠvecDepartment of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, 53209, Czech Republic.
Vlastimil NěmecDepartment of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, 53209, Czech Republic.
Eliška ProcházkováInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, Prague, 160 00, Czech Republic.
Josef CvačkaInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, Prague, 160 00, Czech Republic.
Aleš RůžičkaDepartment of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, 53209, Czech Republic.ORCID https://orcid.org/0000-0001-8191-0273

Funding

Grantová Agentura České Republiky 25-17434S
6 · The paper itself

Abstract

N-heterocyclic phosphines (NHPs), and especially their ionic derivatives, phosphenium cations, have gained significant attention not only as isoelectronic species to N-heterocyclic carbenes (NHCs) but mainly, as highly Lewis acidic, active organocatalysts. A novel type of saturated NHPs has been introduced, with the nitrogen atoms substituted by phosphoramidothioates-{[κ

Indexed as

bond activationN‐heterocyclic phosphinephospheniumtransfer hydrogenation

Identifiers

PMID40736128
PMCPMC12363437

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.