ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025
d-Electron Asymmetry-Driven CN Coupling on Heteronuclear Dual-Atom Catalysts for Sustainable Urea Electrosynthesis.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
2 citing papers in PubMed.
- Engineering of Asymmetric Dual-Atom Sites for Effective Oxygen Electrocatalysis.Nano-micro letters · 2026Review
- d-Electron Asymmetry-Driven CN Coupling on Heteronuclear Dual-Atom Catalysts for Sustainable Urea Electrosynthesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The transition toward carbon-neutral chemical manufacturing calls for innovative strategies to produce nitrogen-based compounds with minimal environmental impact. Urea, a key nitrogen-rich chemical, is currently synthesized via the energy-intensive Bosch-Meiser process, which relies heavily on fossil fuel-derived ammonia. As a sustainable alternative, electrochemical urea synthesis (ECUS) enables the direct coupling of nitrogenous and carbonaceous precursors under ambient conditions, yet remains hampered by sluggish kinetics and poor selectivity-particularly in the critical C─N bond formation step. Here, density functional theory (DFT) calculations is integrated with data-driven machine learning to systematically explore the activity landscape of nitrogen-doped graphene-supported dual-metal-atom catalysts (M'M@NC) for C─N coupling. A comprehensive reaction network is evaluated across 45 M'M@NC configurations, revealing three heteronuclear catalysts-VNi@NC, CoNi@NC and CoCu@NC-with consistently favorable thermodynamic and kinetic performance. Electronic structure analysis indicates that heteronuclear coordination promotes *CO activation and optimizes *NH
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Registered trials
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