ReviewEntropy (Basel, Switzerland)2025
On Enthalpy-Entropy Compensation Characterizing Processes in Aqueous Solution.
Review in Entropy (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- UsingMagnetic resonance letters · 2027Article
- Polymeric Nanoparticles with Surface-Anchored Functional Groups as Chelating Agents for Calcium (CaPharmaceuticals (Basel, Switzerland) · 2025Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The phenomenon of enthalpy-entropy compensation emerges as a ubiquitous feature of processes occurring in water, especially those involving biological macromolecules. In writing the present study, the aim was not to review most of the rationalizations proposed so far but to focus on a general theory of hydration, partly developed and applied by one of us. This theory poses a physical condition for the occurrence of enthalpy-entropy compensation: the energetic strength of the solute-water attraction must be weak compared to that of water-water H-bonds. This condition is largely fulfilled in water due to the cooperativity of its three-dimensional H-bonded network.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.