ArticleNature communications2025
P-stereogenic centre via Pd/Cu-bimetallic catalytic selective phosphinylation of allenylic acetates.
Gen Li, Shichao Hong, Xuechen Li, Wenhao Zhao, Chaobo Ye, Yi Yu, Huajie Jiang, Jie Yu, Xue Zhang, Shengming Ma and 1 more
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In one paragraphArticle in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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11 authors.
Gen LiDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China.
Shichao HongResearch Centre for Molecular Recognition and Synthesis, Department of Chemistry, Fudan University, Shanghai, China.
Xuechen LiDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China.
Wenhao ZhaoDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China.
Chaobo YeDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China.
Yi YuDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China.
Huajie JiangDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China.ORCID http://orcid.org/0000-0001-5165-5072 Jie YuDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China.ORCID http://orcid.org/0000-0002-9968-1429 Xue ZhangState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Shanghai, China. xzhang@sioc.ac.cn.ORCID http://orcid.org/0000-0001-7995-9879 Qiankun LiDepartment of Applied Chemistry, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei, China. liqk@ahau.edu.cn.ORCID http://orcid.org/0000-0002-4826-1926 Funding
National Natural Science Foundation of China (National Science Foundation of China) 92156022Natural Science Foundation of Anhui Province (Anhui Provincial Natural Science Foundation) 2308085Y13
6 · The paper itselfAbstract
P-stereogenic organophosphorus compounds are a class of highly important compounds due to their potentials in asymmetric catalysis both as ligands or catalysts and medicinal chemistry. Herein, we report an efficient protocol under bimetallic catalysis of Pd/Cu for highly regio-, E- and enantioselective phosphinylation of allenylic acetates with racemic secondary phosphine oxides forming a wide range of versatile P-stereogenic 1,3-dienyl phosphine oxides with 86-95% ee. The regioselectivity is unique as compared to the traditional catalytic enantioselective allenylations.
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PMID40715085
PMCPMC12297436
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