ArticleGels (Basel, Switzerland)2025
In Situ Gel-Forming System for the Removal of Ferruginous Deposits on Nanhai I Shipwreck.
Article in Gels (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 authors.
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Abstract
The removal of iron deposits on shipwreck surfaces by mechanical cleaning is labour-intensive work. This study develops an in situ gel and peeling cleaning method, utilising a carboxymethyl chitosan/tannic acid (CMCS/TA) colloidal solution spray on the surface of ferruginous deposits, promoting their removal by adhesion, chelation, and electrostatic bonding processes. The investigation confirmed that the CMTA-2 sample exhibited a sprayable viscosity of 263 mPa/s, the largest single removal thickness of 1.01 mm, a significant reduction in the fe/s atomic ratio by 2.53 units, and enhanced the deposit removal homogeneity. The field testing of the Nanhai I cultural relic showed a 14.37% reduction in iron concentration and a significant decrease in red colour (Δa* = 4.36). The synergistic mechanism involves TA chelating Fe
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