Evidence map›Paper›PMID 40704884›Full record

ArticleJournal of the American Chemical Society2025

Catalytic Borylation of Poly(vinyl chloride) Produces Adhesive Materials.

Kyan A D'Angelo, Nathan Sun, Nicodemo R Ciccia, Isaac F Yu, Brett A Helms, John F Hartwig

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Kyan A D'AngeloDepartment of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.ORCID 0000-0002-9688-5143
Nathan SunDepartment of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.ORCID 0009-0008-2921-2951
Nicodemo R CicciaDepartment of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.ORCID 0000-0002-1379-3789
Isaac F YuDepartment of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.ORCID 0000-0001-9659-2204
Brett A HelmsMaterials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.ORCID 0000-0003-3925-4174
John F HartwigDepartment of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.ORCID 0000-0002-4157-468X

Funding

Acquisition of a Cryoprobe and Related Accessories for a 600 MHz NMR Spectrometer to Support Health Research Activities at the University of California, BerkeleyS10OD024998 · OD · UNIVERSITY OF CALIFORNIA BERKELEY · PI HARTWIG, JOHN F · 2018 to 2018
$265k
Catalyst- and Reagent-Guided Selective Alkyl C-H Bond FunctionalizationF32GM146425 · NIGMS · UNIVERSITY OF CALIFORNIA BERKELEY · PI D'ANGELO, KYAN ANTHONY · 2023 to 2025
$174k
NIGMS NIH HHS F32 GM146425NIH HHS S10 OD024998
6 · The paper itself

Abstract

Postpolymerization functionalization of polymers can create new applications for existing materials, while retaining their most favorable, intrinsic properties. Polyvinyl chloride (PVC) is a widely used, commodity polymer that is particularly challenging to modify. We report a copper-catalyzed protocol that replaces a small fraction of the C-Cl bonds in PVC with C-B bonds to boronic esters. The reaction occurs with an inexpensive catalyst comprising copper(II) chloride and an NHC ligand derived from a common ionic liquid that is distinct from the N-heterocyclic carbene (NHC) used for the borylation of small alkyl halides. The resulting materials adhere strongly to common surfaces, such as glass and metals, even more strongly than do commercial glues.

Identifiers

PMID40704884
PMCPMC12356650

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.