Evidence map›Paper›PMID 40699918›Full record

ArticleJournal of the American Chemical Society2025

Ordering Bent and Straight Dicarboxylate Linkers in an fcu Zirconium Metal-Organic Framework.

Grace S G Farmer, Daniel J Cheney, Khai-Nghi Truong, Nusik Gedikoglu, Bhupendra P Mali, Datta Markad, Dmytro Antypov, Frédéric Blanc, Alexandros P Katsoulidis, Matthew J Rosseinsky

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Grace S G FarmerDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0009-0007-3101-9491
Daniel J CheneyDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.
Khai-Nghi TruongRigaku Europe SE, Hugenottenallee 167, 63263 Neu-Isenburg, Germany.
Nusik GedikogluDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0009-0007-5186-7893
Bhupendra P MaliDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0000-0002-1699-4877
Datta MarkadDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0000-0001-6447-7922
Dmytro AntypovDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0000-0003-1893-7785
Frédéric BlancDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0000-0001-9171-1454
Alexandros P KatsoulidisDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0000-0003-0860-7440
Matthew J RosseinskyDepartment of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K.ORCID 0000-0002-1910-2483

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The ordering of multiple organic linkers with different sizes and geometries on metal-organic frameworks (MOFs) offers structures with advanced complexity and functionality for enhanced properties. The selection of the components and the number of synthesis steps are commonly rationalized to match existing structural motifs in order to increase the probability of producing the designed new frameworks. Alternatively, combining multiple components, without a preconceived structural model, allows for the exploration of unprecedented structural characteristics. However, this approach requires a large number of experiments to identify both the composition and conditions for a successful synthesis. Here, we report a new Zr-MOF containing ordered straight and bent dicarboxylate linkers prepared by a one-pot synthesis. The discovery was made by high-throughput exploration of the chemical space composed of two linkers, the source of Zr, and the modulator. The linkers and the Zr

Identifiers

PMID40699918
PMCPMC12333367

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.