ArticleJournal of the American Chemical Society2025
Ordering Bent and Straight Dicarboxylate Linkers in an fcu Zirconium Metal-Organic Framework.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Synthesis and Characterization of Three-Dimensional Uranyl Coordination Polymers Containing Selenophene and Tellurophene Linkers.Inorganic chemistry · 2026Article
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10 authors.
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Abstract
The ordering of multiple organic linkers with different sizes and geometries on metal-organic frameworks (MOFs) offers structures with advanced complexity and functionality for enhanced properties. The selection of the components and the number of synthesis steps are commonly rationalized to match existing structural motifs in order to increase the probability of producing the designed new frameworks. Alternatively, combining multiple components, without a preconceived structural model, allows for the exploration of unprecedented structural characteristics. However, this approach requires a large number of experiments to identify both the composition and conditions for a successful synthesis. Here, we report a new Zr-MOF containing ordered straight and bent dicarboxylate linkers prepared by a one-pot synthesis. The discovery was made by high-throughput exploration of the chemical space composed of two linkers, the source of Zr, and the modulator. The linkers and the Zr
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