ArticleChemphyschem : a European journal of chemical physics and physical chemistry2025
Quantitative Nuclear Magnetic Resonance Spectroscopy with Overhauser Dynamic Nuclear Polarization.
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Enabling Quantitative BenchtopMagnetic resonance in chemistry : MRC · 2026Article
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Authors and funding
6 authors.
Funding
Abstract
Nuclear magnetic resonance (NMR) spectroscopy is a powerful tool for process monitoring. However, the quantitative analysis of highly diluted components or of components in small sample volumes is difficult with this analytical method due to its inherent lack of sensitivity. The hyperpolarization technique Overhauser dynamic nuclear polarization (ODNP) holds promise to solve this problem because it can provide strong signal enhancements. Furthermore, ODNP operates on short time scales and can therefore be used on flowing samples. Despite these advantages, to our knowledge, ODNP has never been applied for quantitative analysis of mixtures-probably because NMR signal enhancements by ODNP can vary greatly for different molecules, making quantitative analysis of mixtures difficult. We demonstrated that this problem can be solved by a robust calibration: three binary mixtures were studied as test cases in a wide range of concentrations by ODNP-enhanced
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Registered trials
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