ArticleThe journal of physical chemistry letters2025
Polaritonic Control of Blackbody Infrared Radiative Dissociation.
Article in The journal of physical chemistry letters, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Equivalent Modeling and Calculation of the Infrared Characteristics of Combined Multi-Regular Triangular Pyramid Cavity Structures Based on Cavity Radiation Theory.Sensors (Basel, Switzerland) · 2026Article
- A macroscopic condensation theory for vibrational strong coupling effects.Nature communications · 2026Article
- Resonant Enhancement of Photolysis through Plasmon-Vibrational Coupling.Journal of the American Chemical Society · 2026Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Vibrational strong light-matter coupling offers a promising approach for controlling chemical reactivity with infrared microcavities. While recent research has examined potential mechanisms for this phenomenon, many important questions remain, including what type of reactions can be modified and to what extent this modification can be achieved. In this study, we explore the dynamics of Blackbody Infrared Radiative Dissociation (BIRD) in microcavities under weak and strong light-matter interaction regimes. Using a Master equation approach, we simulate the effects of infrared field confinement and polariton formation on BIRD rates for diatomic molecules weakly coupled to the radiation field. We present a framework explaining how infrared microcavities influence BIRD kinetics, highlighting the importance of overtone transitions in the process. Our findings outline conditions under which significant enhancement or mild suppression of BIRD rates can be achieved, offering insights into practical limitations and new strategies for controlling chemistry within infrared resonators.
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Registered trials
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