ArticleNature communications2025
Photocatalytic ethylene production over defective NiO through lattice oxygen participation.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Elucidating Photo-Kinetic Control in Photothermal Reverse Water-Gas Shift Reaction.Angewandte Chemie (International ed. in English) · 2026Article
- Light-induced electronic structure modulation in perovskite ferrite for efficient photothermal dry reforming of methane.Chemical science · 2026Article
- Structure-Activity Relationships in Ni-Al Mixed Oxides: The Critical Role of a Precursor Anion in the Oxidative Dehydrogenation of Ethane.Molecules (Basel, Switzerland) · 2025Article
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Authors and funding
14 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Lattice oxygen-mediated photocatalytic ethane dehydrogenation represents a sustainable strategy for ethylene production, yet achieving a balance between high productivity, selectivity, and durability remains challenging. Here, we report a defective NiO-300 catalyst, where precisely engineered Ni vacancies activate lattice oxygen by weakening Ni-O bond and improving lattice oxygen mobility. This promotes efficient ethane activation and C-H bonds cleavage through photoinduced hole capture, intensifying ethane dehydrogenation via a light-boosted Mars-van Krevelen mechanism. The NiO-300 catalyst manifests a high ethylene yield of 604.5 μmol g
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Registered trials
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