ArticleACS materials Au2025
Tuning Physicochemical Properties of Boron Nitride-Based Membranes via Scalable One-Step Exfoliation for Ionic and Molecular Nanofiltration.
Article in ACS materials Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Two-dimensional (2D) nanomaterials, such as graphene, have been widely used in various applications, such as electrodes for energy storage and laminar membranes for separations. Hexagonal boron nitride (hBN), one of the 2D materials possessing properties similar to graphene, can be used as laminar stacking laminates for separation processes due to its high filtration efficiency and solvent flow. Herein, we prepared 2D-hBN nanosheets using different nitrogen-containing precursors via facile liquid-phase exfoliation for the preparation of hBN membranes. We found that the as-prepared hBN samples exhibit unique physicochemical properties, as determined by various spectroscopic techniques, particularly near-edge X-ray absorption fine structure spectroscopy, which was used to identify the presence of defects on the hBN nanosheets. The elemental compositions of each hBN nanosheet were also revealed by an X-ray photoelectron spectroscopic technique, indicating significant changes in the B:N and B:C ratios. The hBN membranes exhibit high stability in aqueous solutions without membrane deformation. The nanochannel height of the hBN membranes was found to be
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