ArticleThe journal of physical chemistry. B2025
Missing Eutectic Transition in Electrolyte Solutions in Confinement Due to Ion Accumulation in the Interfacial Layer.
Article in The journal of physical chemistry. B, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The anomalous properties of aqueous electrolytes under nanoconfinement are of wide concern due to their widespread occurrence in both natural and industrial processes. Recent studies suggest that the eutectic transition of dilute solutions in nanopores is inhibited. In this work, we propose that the preferential accumulation of dissolved ions in the interfacial layer and the resulting depletion of the ions in the core of the pore solution are the key factors contributing to the absence of salt crystallization at the eutectic point. Systematic calorimetric measurements were conducted with CaCl
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