Evidence map›Paper›PMID 40650666›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2025

Molecular Engineering of Ionic Metal-Organic Frameworks via Ligand Conjugation Modulation for Tailored Phosphorescence and Multilevel Encryption.

Qi Wu, Xinyu Gao, Wenyan Zhang, Yaoyu Wang

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Qi WuKey Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, P. R. China.
Xinyu GaoKey Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, P. R. China.
Wenyan ZhangKey Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, P. R. China.ORCID https://orcid.org/0000-0003-1708-1655
Yaoyu WangKey Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, P. R. China.

Funding

Science and Technology Project of Xi'an 2024JH-CLYB-0054Shaanxi Science and Technology Association 2022GY-384Shaanxi Science and Technology Association 2022JBGS2-07Shaanxi Science and Technology Association 2022QFY06-06Shaanxi Science and Technology Association 2025SYS-SYSZD-076Yunnan Provincial Science and Technology Department YPML-2023050206Yunnan Provincial Science and Technology Department YPML-20240502036
6 · The paper itself

Abstract

The rational design of metal-organic frameworks (MOFs) with tunable phosphorescence remains challenging due to limited understanding of ligand conjugation effects on excited-state dynamics. Herein, two isomorphic ionic MOFs (IMOF-DMF and IMOF-DEF) are constructed via in situ decarbonylation of DMF/DEF, leveraging guest-ion size to regulate ligand conjugation through modulation of pyridine ring dihedral angles. IMOF-DEF exhibits superior room-temperature phosphorescence (RTP) and temperature-dependent behavior. Mechanistic studies reveal that reduced conjugation enhances intersystem crossing (ISC) by strengthening spin-orbit coupling while minimizing the singlet-triplet energy gap (ΔE

Indexed as

information encryptionionic metal‐organic frameworkligand conjugationroom‐temperature phosphorescencestructural regulation

Identifiers

PMID40650666
PMCPMC12533150

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.