Evidence map›Paper›PMID 40644593›Full record

ArticleInorganic chemistry2025

Bromo-Substituted Phenylbenzothiazole Cyclometalating Ligands for the Development of Reverse Saturable Absorption Materials.

Erica S Knorr, Jordan C Kelly, Daniel P Harrison, Catherine J Fabiano, Caitlin G Bresnahan, Ryan B Gaynor, Jack M Harrison, Nanki Verma, Trenton R Ensley, Ryan M O'Donnell and 5 more

Abstract read
In one paragraph

Article in Inorganic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Erica S KnorrU.S. Army Combat Capabilities Development Command Army Research Laboratory, 2800 Powder Mill Rd, Adelphi, Maryland 20783, United States.
Jordan C KellyU.S. Army Combat Capabilities Development Command Army Research Laboratory, 2800 Powder Mill Rd, Adelphi, Maryland 20783, United States.
Daniel P HarrisonDepartment of Chemistry, Virginia Military Institute, 401 Maury-Brooke Hall, Lexington, Virginia 24450, United States.ORCID 0000-0003-1840-2561
Catherine J FabianoDepartment of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77251, United States.
Caitlin G BresnahanU.S. Army Corps of Engineers, Engineer Research and Development Center, 3909 Halls Ferry Rd, Vicksburg, Mississippi 39180, United States.ORCID 0000-0003-3285-9074
Ryan B GaynorU.S. Army Combat Capabilities Development Command Army Research Laboratory, 2800 Powder Mill Rd, Adelphi, Maryland 20783, United States.
Jack M HarrisonDepartment of Chemistry and Life Science, United States Military Academy, 753 Cullum Rd, West Point, New York 10996, United States.
Nanki VermaDepartment of Chemistry and Life Science, United States Military Academy, 753 Cullum Rd, West Point, New York 10996, United States.
Trenton R EnsleyU.S. Army Combat Capabilities Development Command Army Research Laboratory, 2800 Powder Mill Rd, Adelphi, Maryland 20783, United States.
Ryan M O'DonnellU.S. Army Combat Capabilities Development Command Army Research Laboratory, 2800 Powder Mill Rd, Adelphi, Maryland 20783, United States.
Kenneth J SmithFibertek, Inc., 13605 Dulles Technology Dr, Herndon, Virginia 20171, United States.
Peter Y ZavalijDepartment of Chemistry and Biochemistry, University of Maryland, 8051 Regents Drive, College Park, Maryland 20742, United States.ORCID 0000-0001-5762-3469
Thomas N RohrabaughU.S. Army Combat Capabilities Development Command Army Research Laboratory, 2800 Powder Mill Rd, Adelphi, Maryland 20783, United States.ORCID 0000-0001-6652-9781
Chi K NguyenDepartment of Chemistry and Life Science, United States Military Academy, 753 Cullum Rd, West Point, New York 10996, United States.ORCID 0000-0002-6431-6835
Victor A JaffettDepartment of Chemistry and Life Science, United States Military Academy, 753 Cullum Rd, West Point, New York 10996, United States.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Transition metal complexes have seen increased use in applications in the fields of photoredox catalysis, photodynamic therapy, biological sensing, and as phosphors for organic light-emitting diodes. Interest in transition metal complexes as nonlinear optical materials has increased as a result of advances in two-photon absorption and reverse saturable absorption (RSA) characterization techniques and observed characteristics. Iridium(III) organometallic chromophores are of particular interest as transition metal absorbers due to their strong spin-orbit coupling, which provides access to triplet excited states and ligand-based tuning of the molecular orbitals, which enables broad spectral absorption. Herein, new microwave-assisted synthetic methods, physical characterization, and photophysical characterization of a novel series of iridium-cyclometalated with bromo-substituted phenylbenzothiazole (pbt) ligands of the form [Ir(pbt)

Identifiers

PMID40644593
PMCPMC12308814

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.