Evidence map›Paper›PMID 40644318›Full record

ArticleJournal of the American Chemical Society2025

Intramolecular Oxo Atom Migration to the

Deesha D Malik, Shilpa Bhatia, Maike N Lundahl, Haley N Bautel, Dylan M Rogers, Werner Kaminsky, Julie A Kovacs

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Review
  3. Intramolecular Oxo Atom Migration to theJournal of the American Chemical Society · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Deesha D MalikThe Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.ORCID 0000-0001-7800-8852
Shilpa BhatiaThe Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.
Maike N LundahlThe Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.ORCID 0000-0002-4391-7279
Haley N BautelThe Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.
Dylan M RogersThe Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.
Werner KaminskyThe Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.ORCID 0000-0002-9100-4909
Julie A KovacsThe Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.ORCID 0000-0003-2358-1269

Funding

Understanding How Thiolates Promote Dioxygen ChemistryR01GM123062 · NIGMS · UNIVERSITY OF WASHINGTON · PI KOVACS, JULIA A · 2018 to 2025
$3.4M
500 MHz NMR Spectrometer Upgrade and CryoprobeS10OD030224 · OD · UNIVERSITY OF WASHINGTON · PI BREEN, NICHOLAS FRASER · 2022 to 2022
$600k
NIGMS NIH HHS R01 GM123062NIH HHS S10 OD030224
6 · The paper itself

Abstract

Herein, we show for the first time that thiolate ligands can play an important role in promoting 2e- oxo atom transfer with nonheme iron. We examine the mechanism of oxo atom transfer to a

Identifiers

PMID40644318
PMCPMC13475806

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.