ArticleJournal of the American Chemical Society2025
Active Sites under Electronic Effect Are More Sensitive to Microenvironment in CO
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
7 citing papers in PubMed.
- Probing Electrocatalyst Design for Product Selectivity in COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Switchable synthesis of aldehydes and alcohols by hydroformylation with ligand-modified Rh single-atom catalyst.Nature communications · 2026Article
- Article
- Science-Towards-Technology Breakthrough in COAdvanced materials (Deerfield Beach, Fla.) · 2026Review
- Ligand-Modulated Release of Copper Active Sites Extends Ethylene Production in COJournal of the American Chemical Society · 2026Article
- Oxides and Carbonates Accelerate Copper Instability in COJournal of the American Chemical Society · 2026Article
- Cu─O─Al Interfacial Engineering on Cu Nanowires for Durable COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Tailoring the structure of the active sites and engineering the microenvironment to tune catalytic performance are both at the forefront of catalysis. Yet, design principles bridging the two remain missing. Here, we synthesize a platform consisting of well-defined cubic Cu nanocrystals with an oxide coating of tunable porosity, here alumina. We indicate that varying the porosity modulates the relative importance of the native geometric effect and the introduced interfacial electronic effect. We link the change in porosity to the catalytic behavior in the electrochemical CO
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.