ArticleACS nano2025
Mechanically Robust Supercrystals from Antisolvent-Induced Assembly of Perovskite Nanocrystals.
Article in ACS nano, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Deterministic Nucleation of Nanocrystal Superlattices on 2D Perovskites for Light-Funneling Heterostructures.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Spatial Mapping of Electrochemical Hole Injection into Supercrystals of Perovskite Nanocrystals.Nano letters · 2026Article
- One-dimensional CsPbBrNature communications · 2026Article
- Interparticle Ion Migration in Cesium Lead Mixed-Halide Perovskite Nanocrystal Superlattices.Nano letters · 2026Article
- How Antisolvent-Induced Ligand Stripping Shapes CsPbXNano letters · 2026Article
- Sinusoidal Displacement Describes Disorder in CsPbBrACS nano · 2026Article
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Authors and funding
20 authors.
Funding
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Abstract
Ordered arrays of nanocrystals, called supercrystals, have attracted significant attention owing to the collective quantum effects arising from the coupling between neighboring nanocrystals. In particular, lead halide perovskite nanocrystals are widely used because of the combination of the optical properties and faceted cubic shape, which enables the formation of highly ordered supercrystals. The most frequently used method for the fabrication of perovskite supercrystals is based on the self-assembly of nanocrystals from solution via slow evaporation of the solvent. However, the supercrystals produced with this technique grow in random positions on the substrate. Moreover, they are mechanically soft due to the presence of organic ligands around the individual nanocrystals. Therefore, such supercrystals cannot be easily manipulated with microgrippers, which hinders their use in applications. In this work, we synthesize mechanically robust supercrystals built from cubic lead halide perovskite nanocrystals by a two-layer phase diffusion self-assembly with acetonitrile as the antisolvent. This method yields highly faceted thick supercrystals, which are robust enough to be picked up and relocated by microgrippers. We employed X-ray nanodiffraction together with high-resolution scanning electron microscopy and atomic force microscopy to reveal the structure of CsPbBr
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