Evidence map›Paper›PMID 40630115›Full record

ArticleACS catalysis2024

Organobismuth Compounds as Aryl Radical Precursors via Light-Driven Single-Electron Transfer.

Nicholas D Chiappini, Eric P Geunes, Ethan T Bodak, Robert R Knowles

Abstract read
In one paragraph

Article in ACS catalysis, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Activation and C-C Coupling of Aryl Iodides via Bismuth Photocatalysis.Angewandte Chemie (International ed. in English) · 2025
    Article
  4. Article
  5. Review
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Nicholas D ChiappiniDepartment of Chemistry, Princeton University, Princeton NJ, 08544.ORCID 0000-0003-0469-1008
Eric P GeunesDepartment of Chemistry, Princeton University, Princeton NJ, 08544.ORCID 0000-0002-6837-0679
Ethan T BodakDepartment of Chemistry, Princeton University, Princeton NJ, 08544.
Robert R KnowlesDepartment of Chemistry, Princeton University, Princeton NJ, 08544.ORCID 0000-0003-1044-4900

Funding

New Synthetic Methods Enabled by Excited-State Redox ChemistryR35GM134893 · NIGMS · PRINCETON UNIVERSITY · PI Robert R Knowles · 2020 to 2026
$3.8M
Organobismuth Compounds As Universal Precursors for Oxidative and Reductive Radical Group Transfer via Photoredox CatalysisF32GM142190 · NIGMS · PRINCETON UNIVERSITY · PI CHIAPPINI, NICHOLAS D · 2021 to 2022
$88k
NIGMS NIH HHS F32 GM142190NIGMS NIH HHS R35 GM134893
6 · The paper itself

Abstract

A light-driven method for the generation of aryl radicals from triarylbismuth(III) and (V) reagents is described. Aryl radical generation is proposed to occur through ligand-assisted mesolytic cleavage of an organobismuth(IV) intermediate generated from either oxidation of Bi

Indexed as

arylbismutharyl radicalorganobismuthphotochemicalradical generation

Identifiers

PMID40630115
PMCPMC12237399

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.