Evidence map›Paper›PMID 40627589›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Multisite Proton-Coupled Electron Transfer Facilitates Oxidative Photocatalysis in a Molecular Zr-Based Coordination Compound.

Mercedes Moreno-Albarracín, Alvaro M Rodriguez-Jimenez, Omar Nuñez, Pablo Garrido-Barros

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Mercedes Moreno-AlbarracínDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada and Unidad de Excelencia en Química (UEQ), Avda. Fuente Nueva s/n, Granada, 18071, Spain.
Alvaro M Rodriguez-JimenezDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada and Unidad de Excelencia en Química (UEQ), Avda. Fuente Nueva s/n, Granada, 18071, Spain.
Omar NuñezDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada and Unidad de Excelencia en Química (UEQ), Avda. Fuente Nueva s/n, Granada, 18071, Spain.
Pablo Garrido-BarrosDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada and Unidad de Excelencia en Química (UEQ), Avda. Fuente Nueva s/n, Granada, 18071, Spain.ORCID https://orcid.org/0000-0002-1489-3386

Funding

European Union NextGenerationEU/PRTR and "ESF+" PREP2022-000253MICIU/AEI/10.13039/501100011033 PID2022-143153OAI00MICIU/AEI/10.13039/501100011033 and "European Union NextGenerationEU/PRTR" RYC2021-031249-I
6 · The paper itself

Abstract

The development of mediators that harness visible light to drive proton-coupled electron transfer (PCET) offers a promising pathway to achieving challenging redox transformations in a more sustainable manner and with enhanced thermochemical efficiency. However, designing photocatalytic systems based on earth-abundant metals while gaining precise control over their excited-state reactivity remains a significant challenge. Here, deprotonation of the hydroxy ligands in the Zr₃(O)(OH)₃ nodes of a photoactive coordination cage is shown to unlock the photocatalytic oxidation of strong O─H and C─H bonds (70-100 kcal mol⁻

Indexed as

Coordination chemistryHomogeneous catalysisPhotoredox catalysisProton‐coupled electron transferReaction mechanisms

Identifiers

PMID40627589
PMCPMC12435420

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.