Polyesteracetals via TBD Catalyzed Ring-Opening Polymerization.

Jakob Meyer, Natalie E Göppert, Leanne M Stafast, Christine Weber, Ulrich S Schubert

Abstract read

In one paragraph

Article in Macromolecular rapid communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Polyesteracetals via TBD Catalyzed Ring-Opening Polymerization.Macromolecular rapid communications · 2025
Article

4 · The record

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5 · Who and what money

Authors and funding

5 authors.

Jakob MeyerLaboratory of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Jena, Germany.

Natalie E GöppertLaboratory of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Jena, Germany.

Leanne M StafastLaboratory of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Jena, Germany.

Christine WeberLaboratory of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Jena, Germany.

Ulrich S SchubertLaboratory of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Jena, Germany.ORCID https://orcid.org/0000-0003-4978-4670

Funding

Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) 316213987 - SFB 1278German Federal Mistry of Economic Affairs and Climate Action (BMWK) 16LP401003Thüringer Aufbaubank 2016 IZN 0009

6 · The paper itself

Abstract

Polyacetals represent a novel category of degradable polymers, exhibiting remarkable potential for utilization in biomedical and pharmaceutical applications due to their controllable degradation behavior under physiological conditions. The organocatalyst 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was used for the ring-opening polymerization (ROP) of 2-methyl-1,3-dioxane-4-one. Whereas standard reaction conditions, suitable for lactide polymerization resulted in a polyester due to loss of acetaldehyde, the amount of esteracetal repeating units could be tailored by the polymerization conditions. Performing the ROP at -35°C at a monomer concentration of 15 mol L

Indexed as

AcetalsPolyestersPolymersCatalysisDioxanesMolecular StructurePolymerizationAcetalsDioxanesPolyestersPolymersblock copolymersorganocatalysispoly(2‐oxazoline)spolyesteracetalsring‐opening polymerization

Identifiers

PMID40623110

DOI10.1002/marc.202500273

PMCPMC12447686

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