Evidence map›Paper›PMID 40609029›Full record

ArticleChemPlusChem2025

From Green to Brown: Characterization of the Fast Alteration of Modern Greenish Enamels in Glass Windows.

Teresa Palomar, David G Calatayud, Mohamed Oujja, Laura Maestro-Guijarro, Mario Aparicio, Jadra Mosa, Bettina Koppermann, Léonie Seliger

Abstract read
In one paragraph

Article in ChemPlusChem, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Teresa PalomarInstituto de Cerámica y Vidrio (ICV), CSIC, c/Kelsen 5. Campus de Cantoblanco, 28049, Madrid, Spain.ORCID https://orcid.org/0000-0002-3762-8788
David G CalatayudInstituto de Cerámica y Vidrio (ICV), CSIC, c/Kelsen 5. Campus de Cantoblanco, 28049, Madrid, Spain.ORCID https://orcid.org/0000-0003-2633-2989
Mohamed OujjaInstituto de Química Física Blas Cabrera (IQF), CSIC, c/ Serrano, 119, 28006, Madrid, Spain.ORCID https://orcid.org/0000-0003-3757-4043
Laura Maestro-GuijarroInstituto de Química Física Blas Cabrera (IQF), CSIC, c/ Serrano, 119, 28006, Madrid, Spain.ORCID https://orcid.org/0000-0002-0530-3815
Mario AparicioInstituto de Cerámica y Vidrio (ICV), CSIC, c/Kelsen 5. Campus de Cantoblanco, 28049, Madrid, Spain.ORCID https://orcid.org/0000-0003-3024-0593
Jadra MosaInstituto de Cerámica y Vidrio (ICV), CSIC, c/Kelsen 5. Campus de Cantoblanco, 28049, Madrid, Spain.ORCID https://orcid.org/0000-0001-9375-9531
Bettina KoppermannCanterbury Cathedral, 8A The Precincts, Canterbury, Kent, CT1 2EG, UK.
Léonie SeligerCanterbury Cathedral, 8A The Precincts, Canterbury, Kent, CT1 2EG, UK.

Funding

Fundação para a Ciência e Tecnologia from Portugal 2023.05135.RESTARTFundação para a Ciência e Tecnologia from Portugal UIDB/EAT/00729/2020Fundação para a Ciência e Tecnologia from Portugal UIDP/00729/2020Regional Government of Madrid TEC-2024/TEC-39Spanish Ministry of Science, Innovation and Universities RYC2023-045699-ISpanish State Research Agency PID2022-137017OB-I00/AEI/1013039/501100011033
6 · The paper itself

Abstract

In 2009-2014, new glass panels were produced by the Stained-Glass Studio of Canterbury Cathedral (UK) and installed in St Peter's Church (Little Barrington, Burford), St Lawrence's Church (Mereworth, Kent), and Canterbury Cathedral. After a few years, some spots and stains have appeared on the greenish areas of the panels. The common factor is that the panels were produced using the same green enamel. The present work reports on the studies of the observed alterations in green enamels to propose possible degradation mechanisms. These studies are based on using different analytical techniques such as optical microscopy, scanning electron microscopy energy dispersive X-ray spectroscopy, inductively coupled plasma mass spectrometry, laser-induced breakdown spectroscopy, X-ray diffraction, µ-Raman spectroscopy, profilometry, X-ray photoelectron spectroscopy, and UV-vis spectroscopy. The characterization of the fragments from the original panels showed that a brown layer of dark lead compounds was formed on the green enamel. The alteration occurred in a 3-step alteration mechanism divided into Pb

Indexed as

alterationsglassesgreen enamelsleadsstained‐glass windows

Identifiers

PMID40609029
PMCPMC12435163

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.