ArticleJournal of the American Chemical Society2025
Synthesis of Borylated Orphaned Cyclopropanes through a Boron-Enabled Cycloisomerization Reaction.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Borylcyclopropanes: Synthetic Strategies and Applications.Angewandte Chemie (International ed. in English) · 2026Review
- Photogenerated Oxetanes as a Gateway to Uphill Cyclopropanation.Angewandte Chemie (International ed. in English) · 2026Article
- Photoredox-Neutral Platform for Direct Decarboxylative CyclopropanationACS catalysis · 2026Article
- Deuterated Cyclopropanation of Alkenes by Iron Catalysis.Organic letters · 2026Article
- The Curious Case of β-Boryl Triplet States.Trends in chemistry · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Cyclopropanes are important building blocks that are used widely in the pharmaceutical and agrochemical industries. However, synthesizing highly substituted cyclopropanes has proven to be challenging. Herein, we disclose a new strategy to prepare borylated cyclopropanes through the use of a boron-enabled cycloisomerization reaction. The method relies on the generation of a triplet biradical through an energy transfer process. Subsequent 1,2-boron shift leads to the formation of a triplet 1,3-biradical, which is poised to undergo radical recombination in concert with intersystem crossing. The generated borylated cyclopropanes are useful intermediates, as a variety of highly substituted cyclopropanes can be easily prepared.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.