ArticleJournal of the American Chemical Society2025
Too Fast for Spin Flipping: Absence of Chirality-Induced Spin Selectivity in Coherent Electron Transport through Single-Molecule Junctions.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Chiral N-Heterocyclic Carbene On-Surface Induced Electronic Spin Filtration.Journal of the American Chemical Society · 2026Article
- Transmission Eigenvalues in Chiral Molecular Junctions.ACS omega · 2026Article
- Adsorption-Induced Surface Magnetism.ACS nano · 2026Article
- Dipole-Induced Inversion of Spin-Dependent Charge Transport through α-Helical Peptide-Based Single-Molecule Junctions.Journal of the American Chemical Society · 2025Article
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chirality-induced spin selectivity (CISS), which refers to the ability of chiral molecules to preferentially select spins during electron transfer, has attracted great attention during the past two decades. However, the theoretical and experimental understanding of the CISS effect remains preliminary. In this study, we demonstrate that there is no distinguishable CISS effect in the case of coherent electron transport through single chiral molecular junctions for a set of four molecule studied here. Our conclusion is based on statistical evaluations of thousands of single-molecule junctions across four different molecules with different origins of chirality measured by the scanning tunneling microscope-based break-junction technique. The experimental results for all molecules show no dependence on external magnetic field or chirality in both conductance and current-voltage measurements. In addition,
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