ArticleScientific reports2025
Evaluation study on gas-phase passivation inhibiting the spontaneous combustion tendency of ferrous sulfide compounds.
Article in Scientific reports, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 authors.
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Abstract
The iron sulfide compound FeS, present in petrochemical plants, is prone to spontaneous combustion when exposed to air, posing a significant threat to the safety of production processes in the petrochemical industry. Accurately assessing the spontaneous combustion tendency of FeS is crucial for preventing fire and explosion hazards in petrochemical storage tanks. In this study, FeS was passivated with 3%, 6%, and 9% concentrations of passivator for 2 to 8 h, and the effects of gas-phase passivation on FeS were investigated. Thermodynamic and pore structure parameters were extracted through simultaneous thermal analysis and BET specific surface area measurement experiments. The entropy-weight TOPSIS method was then used to evaluate the passivated samples and determine the optimal passivation conditions. The results show that the entropy-weight method assigns dominant weights to the duration temperature in the room-temperature spontaneous combustion stage (ΔT
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