ArticleACS central science2025
A Quantum Chemical Method for Dissecting London Dispersion Energy into Atomic Building Blocks.
Article in ACS central science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
8 citing papers in PubMed.
- London Dispersion in Confined Chiral Ion-Pair Asymmetric Catalysis: From Background Interaction to Design Principle.Accounts of chemical research · 2026Article
- Nickel-Catalyzed Enantioselective Coupling Reactions of Fluorinated Sorbamides with Aldehydes AffordingJournal of the American Chemical Society · 2026Article
- Article
- The Catalytic Asymmetric Mukaiyama-Michael Reaction of Silyl Ketene Acetals with Cyclic Enones: Short Routes to Jasmonates.Journal of the American Chemical Society · 2026Article
- Dispersive Fluorine/Bromine Interactions as Key Selectivity Determinant: Asymmetric Cyclopropanations with 3,3,3-Trifluoro-2-diazopropionate Catalyzed by a Heterochiral-at-The-Metal Centers Dirhodium Paddlewheel Complex.Journal of the American Chemical Society · 2026Article
- Deciphering Asymmetric Induction in Photoredox Catalysis by Chiral Counteranions.ACS catalysis · 2026Article
- LEDAW: An Integrated Software Suite with GUI for Automating Local Energy Decomposition Analysis of Molecular Interactions.Journal of chemical information and modeling · 2025Article
- Broadening the Scope of the ETS-NOCV Scheme: A Versatile Implementation in ORCA.Journal of chemical theory and computation · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
London dispersion (LD) forces are ubiquitous in chemistry and biology, governing processes such as binding of drugs to protein targets, the formation and stability of reaction intermediates, and the selectivity of enantioselective transformations. Developing an experimental or quantum chemical method to quantify atomic contributions to LD energy could open up new pathways for controlling reaction selectivity and guiding molecular design. Herein, we initially introduce Atomic Decomposition of London Dispersion energy (ADLD), a computational method that provides atomic-level resolution in quantifying LD energy at the "gold standard" level of quantum chemistry. Through a series of case studies, we reveal that LD is highly sensitive to variations in the electronic structure, including spin state, charge, and valence bond resonance effectskey factors often overlooked. Furthermore, we uncover the fundamental origin of the recently proposed
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.