ArticleJACS Au2025
Triplet Vinylidenes Based on (Benz)imidazole and 1,2,3-Triazole N‑Heterocycles.
Article in JACS Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
3 citing papers in PubMed.
- Postsynthetic modification of N-heterocyclic diazoolefinsDalton transactions (Cambridge, England : 2003) · 2026Article
- Mesoionic N-Heterocyclic Olefins, Imines, Thiones, Phosphinidenes and Their Application in Catalysis.Angewandte Chemie (International ed. in English) · 2026Review
- Triplet Metallovinylidenes of Palladium and Platinum Based on a Chelating P/Diazoalkene Ligand.Angewandte Chemie (International ed. in English) · 2026Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Triplet vinylidenes, a new class of carbon-centered diradicals containing a monosubstituted carbon atom, remain largely unexplored. A series of triplet vinylidenes based on five-membered heterocycles, featuring 2- and 4-imidazole, benzimidazole as well as 1,2,3-triazole backbones, are generated upon irradiation of stable diazoalkenes and are investigated by electron paramagnetic resonance (EPR) spectroscopy. While the calculated S/T gaps strongly vary (∼9.9-18.4 kcal/mol), the experimental zero-field splitting (ZFS)
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Registered trials
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